Sultana P. Rumi, a Lev N. Zakharov a and Addison N. Desnoyer * a
a Department of Chemistry, Oregon State University, Corvallis, OR, USA
E-mail: addison.desnoyer@oregonstate.edu
Herein, we report the synthesis of a modular family of novel bimetallic tetraamidodiamine (tada) ligands, Li4-R-tada (R = Me3Si, t BuMe2Si, and i Pr3Si). These silylamido ligands display two distinct binding pockets whose steric profiles can be easily tuned by choice of the substituents on silicon. We also show that salt metathesis is a convenient route to install these new ligands on the early transition metals titanium(IV) and vanadium(III).
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S. P. Rumi, L. N. Zakharov and A. N. Desnoyer, Dalton Trans., 2024, Advance Article , DOI: 10.1039/D4DT01840K
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